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@jwisser Of course, the designers at Apple could have drawn this (and any icon) however they wanted to, but the fault here (in my opinion) is the tools and the design direction for app icons.
The tool boxes you into a corner if you “have” to use it to get the style they defined for app icons. If you’re willing to ignore that dynamic lighting, you can have a lot more flexibility. To be sure, they did this to themselves, but I almost can’t blame a designer who has to live with these restrictions.
@jwisser I do not want to defend this style, however—
The artwork is probably not “off-center,” but the specular highlight on Liquid Glass layers is inset. The inset begins from the edge of each shape (where the highlight stops on the bigger portion of the pie chart). The *highlight* does not start at that edge.
If this were a traditionally rendered icon, a designer might have done it differently.
The result looks off-center, but the shapes are likely not. Higher resolution examples: